Acta Chemica Malaysia

Journal: Acta Chemica Malaysia (ACMY)
Author: Adegoke Idowu A., Ogunsanwo O.Y and Ige Ayodeji R
ISSN: 2576-6732
e-ISSN: 2576-6724

This is an open access journal distributed under the Creative Commons Attribution License CC BY 4.0, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited

DOI: 10.2478/acmy-2021-0006

Nigeria demand for sustainable, affordable and accessible energy is on the rise. Hence, this led to rigorous research to determine affordable processes of using waste materials for production of sustainable energy. In this research pyrolysis was carried out in a fabricated fixed bed pilot-scale reactor using Gmelina arborea (sawdust) biomass for the production of bio-oil. The physical, chemical properties and the ultimate analysis of the bio oil produced were determined following standard methods. The physicochemical properties and ultimate analysis obtained were favourable. The highest moisture content of 21 % at 600 oC and least moisture content of 12 % at 900 oC were obtained from Gmelina arborea. The elemental results of the products show low sulphur quantity which is of good prospects that Gmelina arborea are good materials for bioenergy production without posing danger to the environment. Utilisation of Gmelina arborea for bio-oil production as an alternative fuel would shun unfavourable environmental abasement related to the use of conventional fuels.

Journal: Acta Chemica Malaysia (ACMY)
Author: S. Munir, A. Gul
ISSN: 2576-6732
e-ISSN: 2576-6724

This is an open access journal distributed under the Creative Commons Attribution License CC BY 4.0, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited

DOI: 10.2478/acmy-2021-0005

Metal Nanoparticles show specific physical and chemical properties attributed to its small size and high surface area to volume ratio. These chemical and physical properties using different strategies and conditions enhance its biological application especially in the field of medicine. Earth abundant and cheap cupper metal is the essential element in many processes and has been used as a focus element to synthesize nanoparticles by different methods using new technology, which are being broadly classified as biological methods that includes green synthesis, microorganism etc. and the non-biological synthesis which includes chemical and Physical methods. Thus, the imperative need to synthesize cupper nanomaterial that are economic and efficient is necessary. This review have briefly described the modern methods to synthesize nanoparticles particularly focusing on the non-biological methods of cupper nanoparticles. An overview of current methodologies that are used for cupper nanoparticle mainly chemical reduction using organic and inorganic solvents, Reverse micelle, microemulsion, polyol method and several physical methods such as vapor condensation, photo irradiation and plasma synthesis methods are discussed.

Journal: Acta Chemica Malaysia (ACMY)
Author: Nworie Felix Sunday
ISSN: 2576-6732
e-ISSN: 2576-6724

This is an open access journal distributed under the Creative Commons Attribution License CC BY 4.0, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited

DOI: 10.2478/acmy-2021-0004

Microplastic (MP) is currently a subject of discussion in all parts of the world because it has increasingly over the years become the dominant source of pollution in marine ecosystem. Huge number of these Mps emanate from waste management, decommissioning of ships and oil rigs, plastic products in aquaculture and fishery, sewage treatment, consumer products, agricultural production, transportation, offshore oil and gas production and city dust and wears. Microplastic are characteristically non- biodegradable or durable, exhibits buoyancy, travel long distances, complex with toxic chemicals and bioaccumulate being invisible to the human eye. Classification of MPs into primary and secondary based on source and established standard protocols visavis the sampling and identification in matrices were critically reviewed. Physicochemical processes for identification of MPs such as pyrolysis-Gas chromatography/Mass spectrometry, FTIR, Raman spectroscopy, SEM-GS and TGA/MS were reviewed. Deleterious chemicals such as polychlorinated biphenyls (PCBs), polybrominated diphenyl ethers (PBDEs), dioxins, phthalates, polycyclic aromatic hydrocarbons (PAHs) and persistent organic chemicals (POCs) associated with MPs and mechanisms of chelation were appraised. Several menace and health hazards such as hepatic inflammation, genetic mutation, increase in reactive oxygen species (ROS) /oxidative stress, tissue necrosis and proliferation of cells linked with MPs were also discussed. Furthermore, green approaches to arresting the menace such as replacing polymer products with biopolymer an eco-friendly alternative, recycling of plastic products, use of paper bags and glass materials and abrogation of consumer products laced with microbeads were advocated.