Acta Chemica Malaysia

Journal: Acta Chemica Malaysia (ACMY)
Author: Chinyere B. C. Ikpa, Samuel O. Onoja and Anastasia O. Okwaraji

ISSN: 2576-6732
e-ISSN: 2576-6724

This is an open access journal distributed under the Creative Commons Attribution License CC BY 4.0, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited

DOI: https://doi.org/10.2478/acmy-2020-0009

This study aims to synthesize hybrid compounds “via” the coupling of sulphonamide and benzothiazole into one structure that may have improved antibacterial property. The N-(biphenyl-4-yl) thiourea (1) used for the synthesis of the targeted sulphonamides was obtained by reacting diphenylamine and ammonium thiocyanate at room temperature. Cyclization of N-(biphenyl-4-yl)thiourea gave 2-amino-6-phenylbenzothiazole (2) which reacted with benzenesulphonyl chloride and para-toulene sulphonyl chloride to give the targeted sulphonamides (3a & 3b). The synthesized compounds were characterised using melting point, infra-red spectroscopy, nuclear magnetic resonance and elemental analysis. Anti-bacterial screening of the synthesised compounds indicated that all the compounds showed anti-bacterial properties, except 2-amino-6-phenylbenzothiazole that did not show any activity on Escherichia coli.

Journal: Acta Chemica Malaysia (ACMY)
Author: M.N. Yesmin, M.A.K. Azad, M. Kamruzzaman and M.N. Uddin

ISSN: 2576-6732
e-ISSN: 2576-6724

This is an open access journal distributed under the Creative Commons Attribution License CC BY 4.0, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited

DOI: https://doi.org/10.2478/acmy-2020-0008

Bangladesh produces a large amount of corn, pumpkin and carrots every year. To meet its huge energy demand and to lessen dependence on traditional fossil fuel these products are cost effective, renewable and abundant source for bioethanol production. The research was aimed to evaluate Bangladeshi corn, rotten carrot and pumpkin for bioethanol production. About 100 g of substrates was mixed with 300 ml distilled water and blended and sterilized. All the experiment was conducted with a temperature of 35oC, pH 6.0 and 20% sugar concentration. For fermentation, 200 ml yeast (Saccharomyces cerevisiae CCD) was added to make the total volume 500 ml. Addition of small amount of 1750 unit α-amylase enzyme to the substrate solution was found to enhance the fermentation process quicker. After 6- days of incubation, corn produced 63.00 ml of ethanol with 13.33 % (v/v) purity. Bioethanol production capacity of two different local varieties of pumpkin (red and black color) was assessed. Red pumpkin (Cucurbita maxima L.) produces 53 ml of ethanol with purity 6 %v/v and black color pumpkin produces 40 ml of yield with a low purity 4 %v/v. Carrot (Daucus carota L.) produces 73.67 ml of ethanol with 12.66 % (v/v) purity.

Journal: Acta Chemica Malaysia (ACMY)
Author: Muhammad Ali, Qura Tul Ain and Ji HuanHe

ISSN: 2576-6732
e-ISSN: 2576-6724

This is an open access journal distributed under the Creative Commons Attribution License CC BY 4.0, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited

DOI: https://doi.org/10.2478/acmy-2020-0007

World health organization (WHO) data shows that air pollution kills an estimated seven million people worldwide every year. A nanofiber based biodegradable facemask can keep breath from smoke and other particles suspended in the air. In this study, we propose branched polymeric nanofibers as a biodegradable material for air filters and facemasks. Fibers have been elecrospun using double bubble electrospinning technique. Biodegradable polymers, PVA and PVP were used in our experiment. Two tubes, each filled with one of the polymers, were supplied with air from the bottom to form bubbles of polymer solutions. DC 35-40 kV was used to deposit the fibers on an aluminum foil. Results show that the combination of polymers under specific conditions produced branched fibers with average nanofibers diameter of 495nm. FT-IR results indicate the new trends in the graph of composite nanofibers.